Named as one of the 12 apostles:
Matthew 10:3 Philip, and Bartholomew; Thomas, and Matthew the publican; James the son of Alphaeus, and Lebbaeus, whose surname was Thaddaeus;
Mark 3:18 And Andrew, and Philip, and Bartholomew, and Matthew, and Thomas, and James the son of Alphaeus, and Thaddaeus, and Simon the Canaanite,
Luke 6:15-16 Matthew and Thomas, James the son of Alphaeus, and Simon called Zelotes, And Judas the brother of James, and Judas Iscariot, which also was the traitor.
Only three allowed to follow:
Mark 5:37 And he suffered no man to follow him, save Peter, and James, and John the brother of James.
Only three at the transfiguration:
Mark 9:2 And after six days Jesus taketh with him Peter, and James, and John, and leadeth them up into an high mountain apart by themselves: and he was transfigured before them.
Last mentioned, after the ascension of the Lord, in the upper room:
Acts 1:13 And when they were come in, they went up into an upper room, where abode both Peter, and James, and John, and Andrew, Philip, and Thomas, Bartholomew, and Matthew, James the son of Alphaeus, and Simon Zelotes, and Judas the brother of James.
The following references to JAMES would appear to be the half-brother of the Lord Jesus (Matthew 13:55, Mark 6:3):
Acts 12:17 But he, beckoning unto them with the hand to hold their peace, declared unto them how the Lord had brought him out of the prison. And he said, Go shew these things unto James, and to the brethren. And he departed, and went into another place.
Acts 15:13 And after they had held their peace, James answered, saying, Men and brethren, hearken unto me:
Acts 21:18 And the day following Paul went in with us unto James; and all the elders were present.